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Synthesis of Unusual Oxime Ethers by Reaction of Tetranitromethane with B-Alkylcatecholboranes

✍ Scribed by Monique Lüthy; Kurt Schenk; Philippe Renaud


Book ID
101837577
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
293 KB
Volume
16
Category
Article
ISSN
0947-6539

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✍ Shatzmiller, Shimon ;Lidor, Ramy ;Babar, Eliezer 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 283 KB

## Abstract Regiocontrolled deprotonation (e. g. lithiation) of acetone __O__‐methyloxime (1), 5,6‐dihydro‐3‐methyl‐4__H__‐1,2‐oxazine (9a) and 4,5‐dihydro‐3‐methylisoxazole (9b) is achieved within 1 minute at −65°C in hexane/THF. The lithiated compounds react very fast at low temperature (−65°C) w