A straightforward three step route to (1S,2R)-and (1R,2R)-[2H]-glycerols la and lb is reported. The key asymmetric step involves an AD-mix-l~ dihydroxylation on deuterium labelled Z-and E-allyl benzoates 4a and 4b. The route should facilitate the use of [2H]-glycerols la-ld in high enantiomeric puri
✦ LIBER ✦
Synthesis of Unsymmetrically Substituted Phosphane Oxides (R 1 R 2 P(O)H) and Phosphinous Acids (R 1 R 2 POH)
✍ Scribed by Allefeld, Nadine; Grasse, Michael; Ignat'ev, Nikolai; Hoge, Berthold
- Book ID
- 121840622
- Publisher
- John Wiley and Sons
- Year
- 2014
- Tongue
- English
- Weight
- 650 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0947-6539
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