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Synthesis of tritium-labeled (3)-O-(3-hydroxypropyl)-17α-estradiol chromium tricarbonyl: The first radioactive transition metal carbonyl steroid hormone

✍ Scribed by Siden Top; Anne Vessieres; Gérard Jaouen


Publisher
John Wiley and Sons
Year
1987
Tongue
French
Weight
347 KB
Volume
24
Category
Article
ISSN
0022-2135

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✦ Synopsis


3-0-(3-hydroxypropyI)-l7P-estradiol chromium tricarbonyl 1 has been labeled in the 17a

position with deuterium or tritium. These complexes were prepared by reduction of the corresponding estrone by NaBD4 or NaB[3HJ4. The radioactive hormone was obtained in a solid state with a specific activity of 4.1 Ci/mmole, which is sufficiently high for hormone receptor binding studies.