Synthesis of trioxilins B3 from hepoxilins B3
โ Scribed by Ljudmila L. Vasiljeva; Kasimir K. Pivnitsky
- Book ID
- 111729886
- Publisher
- Royal Society of Chemistry
- Year
- 1996
- Tongue
- English
- Weight
- 184 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0959-9436
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๐ SIMILAR VOLUMES
Suwry : Bath C(10) diastereaners of trioxilin R , ll(R),12(R)-trihydro~eicosa-5(2),8(2),14(Z)-trien~ic &.:671-677 (1950). Except as noted, satisfactory spectral data were obtained for all new compounds usfng chromatographfcally homogeneous samples.
Abetract' To characterise the individual epimers of hepoxilin Bs, a new total synthesis procedure was developed consisting of subsequent condensations of enantromerically pure (2R,3S)-epoxy-5-undecynal with LiCmXXxCl and HCrC(C?iz)aC~Me, followed by Lindlar hydrogenation, and finally epimer separati