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Synthesis of Trifluorostyrene Derivatives by Palladium-Catalyzed Cross-Coupling of Lithium Trimethoxy(trifluorovinyl)borate with Aryl Bromides

✍ Scribed by Sasa Duric; Bernd M. Schmidt; Nina M. Ninnemann; Prof. Dr. Dieter Lentz; Prof. Dr. C. Christoph Tzschucke

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
268 KB
Volume
18
Category
Article
ISSN
0947-6539

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✦ Synopsis

Scheme 1. Synthesis of trifluorovinylarenes by cross-coupling. Scheme 2. Preparation of lithium trimethoxy(trifluorovinyl)borate 1 from HFC-134a.

📜 SIMILAR VOLUMES

Regioselective synthesis of aryl hydrazi
Regioselective synthesis of aryl hydrazides by palladium-catalyzed coupling of t-butylcarbazate with substituted aryl bromides
✍ Zhongren Wang; Renato T. Skerlj; Gary J. Bridger 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 207 KB

Substituted aryl bromides are coupled with t-butylcarbazate in the presence of a palladium catalyst and base to afford regioselectively, the corresponding amidation product or amination product depending upon the position of the substituents on the aryl bromide.