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Synthesis of tricyclic bridgehead olefins related to the core structure of CP-225,917 and CP-263,114—solvent, strain, and substitution effects on siloxy-Cope rearrangements

✍ Scribed by Derrick L.J. Clive; Shaoyi Sun; Xiao He; Junhu Zhang; Vanessa Gagliardini


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
333 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis


Siloxy-Cope rearrangements have been used to make bridgehead olefins, such as 15, 16b, 23b and 36-all related to the core of 114.