## Abstract Multiblock copolymers were synthesized through condensation reactions of end‐groups of α,ω‐dichloro‐poly(methylphenylsilylene) with hydroxyl end‐groups of poly(ethylene glycol) or the chain‐ends of ‘living’ polyisoprenyl disodium. Optimum conditions have been sought through kinetic stud
✦ LIBER ✦
Synthesis of Tri- and Multiblock Polymers with Asymmetric Poly(ethylene oxide) End Blocks
✍ Scribed by Touris, Athanasios; Lee, Sangwoo; Hillmyer, Marc A.; Bates, Frank S.
- Book ID
- 121227046
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 940 KB
- Volume
- 1
- Category
- Article
- ISSN
- 2161-1653
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## Abstract **Summary:** Poly(ethylene oxide)‐__block__‐poly(methylidene malonate 2.1.2) block copolymer (PEO‐__b__‐PMM 2.1.2) bearing an allyl moiety at the poly(ethylene oxide) chain end was synthesized by sequential anionic polymerization of ethylene oxide (EO) and methylidene malonate 2.1.2 (MM