๐”– Bobbio Scriptorium
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Synthesis of three stereoisomers of 2-deoxystreptamine

โœ Scribed by H.H. Baer; R.J. Yu


Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
170 KB
Volume
8
Category
Article
ISSN
0040-4039

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Altholactone 1 and (+)-7-epi-altholactone 3 were constructed from Dgulonolactone whereas their respective enantiomers (-)-altholactone 2 and (-)J-epialtholactone 4 were synthesised from D-mannose, involving stereocontrolled reduction of the lactols 21 and 12 as a key step. 'I-epi-altholactone 3, an