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Synthesis of Thiourea−Oxazolines, a New Class of Chiral S,N-Heterobidentate Ligands: Application in Pd-Catalyzed Asymmetric Bis(methoxycarbonylation) of Terminal Olefins

✍ Scribed by Liang, Bo; Liu, Jing; Gao, Ying-Xiang; Wongkhan, Kittiya; Shu, Dong-Xu; Lan, Yu; Li, Ang; Batsanov, Andrei S.; Howard, Judith A. H.; Marder, Todd B.; Chen, Jia-Hua; Yang, Zhen

Book ID
120402548
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
258 KB
Volume
26
Category
Article
ISSN
0276-7333

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ChemInform Abstract: Synthesis of Thiour
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✍ Jia-Hua Chen; et al. et al. 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

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A Thiourea-Oxazoline Library with Axial
A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins
✍ Ying-Xiang Gao; Le Chang; Hang Shi; Bo Liang; Kittiya Wongkhan; Duangduan Chaiya 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 380 KB 👁 2 views

## Abstract We report herein the synthesis of novel chiral S,N‐heterobidentate thiourea‐oxazoline ligands and their application to palladium‐catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. Copper salts were found to play multiple roles in this reacti