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Synthesis of thiophene/phenylene co-oligomers. III. thienyl-capped oligophenylenes

โœ Scribed by S. Hotta

Publisher
Journal of Heterocyclic Chemistry
Year
2001
Tongue
English
Weight
46 KB
Volume
38
Category
Article
ISSN
0022-152X

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โœฆ Synopsis

Abstract

The author reports the synthesis of thienylโ€capped oligophenylenes via improved synthetic schemes. These schemes are based on either the Grignard or Suzuki coupling reaction and enable the author to obtain the target compounds at appreciably high yields. Regarding several of these compounds, their synthesis and characterization are believed to be reported for the first time. The resulting materials have been fully characterized through the nmr and ir spectroscopy. The ir analysis is particularly useful in characterizing the materials of higher molecular weight, since those materials are difficult to dissolve in organic solvents.

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