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Synthesis of Thiophene-Substituted 3H-Naphtho[2,1-b]pyrans, Precursors of Photomodulated Materials

✍ Scribed by Corinne Moustrou; Nicole Rebière; André Samat; Robert Guglielmetti; Abd Errahim Yassar; Roger Dubest; Jean Aubard


Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
632 KB
Volume
81
Category
Article
ISSN
0018-019X

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The photochromic parameters of a set of 26 thiophene-substituted [3H]-naphtho[2,1-b]pyrans were studied by flash photolysis. The experimental results obtained along with molecular modelling approaches (molecular mechanics and quantum calculations) allowed us to propose structure-property relationshi

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## Abstract magnified image Naphtho[2,1‐__b__]pyran nuclei are prevalent in natural products with significant biological and medicinal properties. 3,3‐Disubstituted 3__H__‐naphtho[2,1__‐b__]pyrans are photochromic and find use in electronic display systems, ophthalmic lenses, optical switches, and