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Synthesis of thiolane from tetrahydrofuran and H2S in the presence of proton-donor catalysts

✍ Scribed by Desyatov, I. V. ;Mashkina, A. V.

Book ID
112685361
Publisher
Springer
Year
1991
Tongue
English
Weight
223 KB
Volume
44
Category
Article
ISSN
0133-1736

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Catalytic synthesis of thiolane from tet
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Tetrahydrofuran recyclization to thiolane (the Yuriev reaction) was studied in the presence of alumina. Thiolane formation at 200-500Β°C was found to be accompanied by cracking of both the initial matter and the product, yielding hydrocarbons and coke deposition on the catalyst surface. Catalysts of