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Synthesis of thiocyanohydrins from epoxides using quaternized amino functionalized cross-linked polyacrylamide as a new solid–liquid phase-transfer catalyst

✍ Scribed by Bahman Tamami; Hossein Mahdavi

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
92 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

)acrylamido]trimethyl ammonium chloride resin was developed as a new polymeric phase-transfer catalyst. This quaternized polyacrylamide catalyzed the regioselective ring opening of epoxides by thiocyanate ion to give thiocyanohydrins in high yields under mild conditions.

📜 SIMILAR VOLUMES

Synthesis of azidohydrins from epoxides
Synthesis of azidohydrins from epoxides using quaternized amino functionalized cross-linked polyacrylamide as a new polymeric phase-transfer catalyst
✍ B Tamami; H Mahdavi 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 94 KB

Poly[N-(2-aminoethyl )acrylamido]trimethyl ammonium chloride resin was developed as a new polymeric phase-transfer catalyst. This quaternized polyacrylamide-catalyzed the regioselective ring opening of epoxides by azide ion to give azidohydrins in high yield under mild conditions.