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Synthesis of Thiamacrocycles and Conformational Studies on Their Precursors

โœ Scribed by Abramovitch, Rudolph A.; Ye, Xiaocong; Pennington, William T.; Schimek, George; Bogdal, Dariuz


Book ID
126999451
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
149 KB
Volume
65
Category
Article
ISSN
0022-3263

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Conformational studies on helicenes VII.
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## Abstract Irradiation of 2,7โ€distyrylnaphthalene or 2โ€styrylbenzo[__c__]phenanthrene under completely oxygenโ€free conditions gives rise to the formation of 5,6โ€dihydrohexahelicene (**2**) as a consequence of Hโ€shifts in the primary formed cyclization product. The conformation of **2** was analyse