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Synthesis of Thiabicyclic Heterocycles Through Free Radical Cyclization of β-Thioacrylates

✍ Scribed by Yaroslav V. Bilokin; Artem Melman; Valérie Niddam; Bellinda Benhamú; Mario D. Bachi

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
226 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

Aza-3-thiabicyclo[4.3.0]

nonanes 7 and 8, 3-thiabicyclo[4.4.0]decanes 18, and 8-thiabicyclo[4.3.0]nonanes 31 were obtained from monocyclic precursors through free radical cyclizations involving a b-thioacrylate system as radical acceptor and a thionocarbonate as radical precursor. Oxidative sulfur extrusion in 3-thiabicyclo[4.4.0]decanes 18 afforded methyl (2-isopropenyl-5-methylcyclohexyl)-2propenoates 35.

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ChemInform Abstract: Synthesis of Hetero
ChemInform Abstract: Synthesis of Heterocycles by Radical Cyclization
✍ W. Russell Bowman; Colin F. Bridge; Philip Brookes 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 2 views

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