Second-generation stereoselective synthesis of octahydm~uinoliue 3, a potential key intermediate for the projected synthesis of the nattnl enantion3er of morphine, has been accomplished in five steps from areue c/s-diol 8. Electmchemi~ oxidation of 9b furnished 7b, a precursor for the key benzoate-a
β¦ LIBER β¦
Synthesis of the Tetracyclic Core of Berkelic Acid Using Gold(I)-Catalyzed Hydroarylation and Oxidative Radical Cyclizations
β Scribed by Brimble, Margaret A.; Haym, Isabell; Sperry, Jonathan; Furkert, Daniel P.
- Book ID
- 120407015
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 471 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1523-7060
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