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Synthesis of the piperidinone metabolites of piperidine type phenothiazine antipsychotic drugs via ruthenium tetroxide oxidation

โœ Scribed by G. Lin; K. K. Midha; E. M. Hawes


Book ID
112129903
Publisher
Journal of Heterocyclic Chemistry
Year
1991
Tongue
English
Weight
355 KB
Volume
28
Category
Article
ISSN
0022-152X

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A multistep synthetic route to (~)-10-[2-(1-methyl-2-piperidinyl)ethyl]-2-methylthio-lOH-phenothiazine (thioridazine) was developed which allowed for the incorporation of two deuterium atoms in the piperidine ring and a further two in the 1-position of the ethyl side chain. The key steps involved ru