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Synthesis of the pheromone of the comstock mealybug via a sila-cope elimination

โœ Scribed by Yagamare Fall; Nguyen Van Bac; Yves Langlois


Book ID
104218942
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
176 KB
Volume
27
Category
Article
ISSN
0040-4039

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The use of a Sila-Cope elimination afforded a Z,Z,Z trienamine derivative, direct synthetic precursor of (3Z,6Z,9Z)-3,6,9\_nonadecatriene 1, one of the pheromone components of Bourmia selenaria. X-ray analysis of the tetrahydropyridinium salt 13 leading to the dienic vinyl silane 14 allowed the dete