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Synthesis of the new organometallic carboxylic acid complexes [η5-C5H4COOH)M(CO)nMe] (M  Mo, n = 3; M  Fe, n = 2 and their potential as bioconjugates

✍ Scribed by Bouchra El Mouatassim; Hani ElAmouri; Michèle Salmain; Gérard Jaouen

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 263 KB
Volume: 479
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(94)84121-7

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## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C