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Synthesis of the Hexasaccharide Fragment of Landomycin A: Application of Glycosyl Tetrazoles and Phosphites in the Synthesis of a Deoxyoligosaccharide

✍ Scribed by Guo, Yu; Sulikowski, Gary A.


Book ID
127036487
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
188 KB
Volume
120
Category
Article
ISSN
0002-7863

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Glycosyl Imidates, 61. – Synthesis of th
✍ Han, Xiao-Bing ;Jiang, Zi-Hua ;Schmidt, Richard R. πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 636 KB

## Abstract Reaction of __O__‐(3‐__O__‐methylglucosyl) trichloroacetimidate 2a as glycosyl donor and 1,2:5,6‐di‐__O__‐isopropylidene‐D‐glucofuranose (3) as glycosyl acceptor furnished in the presence of TMSOTf as catalyst the β‐(1β†’3)‐connected disaccharide 5a. Similarly, from __O__‐quinovosyl trich