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Synthesis of the Cyclopentenylamine Derivatives Promoted by SmI2

✍ Scribed by Xu Xiao-Liang; Zhang Yong-Min


Book ID
102097487
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
265 KB
Volume
21
Category
Article
ISSN
0256-7660

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ChemInform Abstract: Synthesis of 2-Viny
✍ J. M. AURRECOECHEA; B. LOPEZ πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

Synthesis of 2-Vinylcyclopentanols by SmI 2 /Pd(0)-Promoted Carbohydrate Ring-Contraction. -Treatment of methyl 5-vinylpyranosides such as (I) with SmI 2 in the presence of catalytic Pd(0) results in ring contraction and direct transformation of the carbohydrate structure into functionalized carboc