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Synthesis of the Cyclobutanone Core of Solanoeclepin A via Intramolecular Allene Butenolide Photocycloaddition.

โœ Scribed by Bui T. B. Hue; Jan Dijkink; Sanne Kuiper; Kimberly K. Larson; Frank S. Jr. Guziec; Kees Goubitz; Jan Fraanje; Henk Schenk; Jan H. van Maarseveen; Henk Hiemstra


Book ID
101956782
Publisher
John Wiley and Sons
Year
2004
Weight
83 KB
Volume
35
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Synthesis of the Tricyclic Core of Solan
โœ B. T. Buu Hue; Jan Dijkink; Sanne Kuiper; Sjoerd van Schaik; Jan H. van Maarseve ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 202 KB

## Abstract Studies are reported towards the synthesis of solanoeclepin A (**1**), the hatching agent of potato cyst nematodes. Two approaches are investigated to access the tricyclic core including the intricate bicyclo[2.1.1]hexanone moiety. The first approach is based on the intramolecular [2+2]