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Synthesis of the Core Compound of the BODIPY Dye Class: 4,4′-Difluoro-4-bora-(3a,4a)-diaza-s-indacene

✍ Scribed by Alexander Schmitt; Babette Hinkeldey; Mandy Wild; Gregor Jung

Book ID
106412668
Publisher
Springer
Year
2008
Tongue
English
Weight
248 KB
Volume
19
Category
Article
ISSN
1053-0509

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## Synthesis of 3,5-Diaryl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY r ) Dyes. -Condensation of arylpyrroles (IV), prepared via Suzuki coupling of arylboronic acids (II) to bromo pyrrole (I), gives highly colored dipyrrolemethenes (VI). Finally, addition of BF 3 -etherate leads to format

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In the title compound, C 10 H 9 BF 2 N 2 , a boron-dipyrromethene (BODIPY) dye, a network of C-HÁ Á ÁF interactions help to establish the crystal packing. The asymmetric unit consists of two molecules.