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Synthesis of the A/B/C Ring System of Taxane Diterpenes from (S)-(+)-Carvone

โœ Scribed by Nagaoka, Hiroto; Hirai, Yoshimasa; Ito, Kennosuke


Book ID
125477345
Publisher
Japan Institute of Heterocyclic Chemistry
Year
1998
Tongue
English
Weight
111 KB
Volume
48
Category
Article
ISSN
0385-5414

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โœ Holton, Robert A. ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 293 KB
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Bicyclo[5.3.l]undecenone 2 corresponding to A and B rings in taxane diterpenes was synthesized. The eight-membered ring was constructed by a baseinduced intramolecular cyclization of twelve-membered lactam sulfoxides 15. 204 lja,b ya,bl,b2 isomer NC-S J K \*H,6 5 4 9 07 / 11' 1 3 10 -. 2 0 H R NHMe