๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Synthesis of the 5-7-6 Core of Guanacastepenes. Construction of C8 Quaternary Carbon via the Inversion of Stereochemistry

โœ Scribed by Nguyen, Truc M.; Seifert, Robert J.; Mowrey, Dale R.; Lee, Daesung


Book ID
121709135
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
92 KB
Volume
4
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Progress towards the total synthesis of
โœ Truc M. Nguyen; Daesung Lee ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 74 KB

The construction of the 5-7-6 tricyclic skeleton of guanacastepene A, including the quaternary carbons, has been achieved. The C-11 and C-8 quaternary carbons were constructed by cuprate addition and carbene insertion, respectively. The 5-7-6 tricyclic core was generated by a selective aldol and SmI