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Synthesis of the 3a,8a-dihydrofuro[2,3-b]benzofuran-2(3H)-one and 1,3,3a,8a-tetrahydro-2H-benzofuro[2,3-b]pyrrol-2-one ring systems from 4-formylcoumarin via acyllactone and iminolactone rearrangements

✍ Scribed by Connor, David T.; Von Strandtmann, M.


Book ID
118196640
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
438 KB
Volume
38
Category
Article
ISSN
0022-3263

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The crystal structure of the title benzofuran derivative, C~16~H~23~NO~3~, has been elucidated. The tricyclic core, __i.e.__ the tetrahydrobenzo–dihydrofuro–pyrrolidine ring system, is non-planar owing to the folding of the five-membered rings at their __cis__ junction. The cyclohexene ring assumes