Synthesis of tetrahydro- and perhydro-dendrolasin
✍ Scribed by A. Quilico; P. Grünanger; F. Piozzi
- Publisher
- Elsevier Science
- Year
- 1957
- Tongue
- French
- Weight
- 879 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
## Dendrolasinl was synthesized from farnesol via biogenetic-type intermediates. ## Farnesol(J) was converted to epoxyfarnesol(3) under standard Sharpless conditions. 2 Lithium diethylamide in boiling benzene cleanly converted 3 to triene-
## Abstract For Abstract see ChemInform Abstract in Full Text.
Perhydrofuro-2,3b furans have been prepared in high yield by radical cyclisation of unsaturated bromo acetals. Their transformation into tetrahydro derivatives is described along with a radical annelation to 2,3-dihydrofurans by tributyltin iodoacetate.