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Synthesis of Tetraarylthiophenes by Regioselective Suzuki Cross-Coupling Reactions of Tetrabromothiophene.

✍ Scribed by Thanh Tuan Dang; Nasir Rasool; Thanh Tung Dang; Helmut Reinke; Peter Langer

Publisher: John Wiley and Sons
Year: 2007
Weight: 30 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200718111

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## Abstract The Suzuki reaction of tetrabromothiophene with arylboronic acids provides a regioselective approach to various 5‐aryl‐2,3,4‐tribromothiophenes, symmetrical 2,5‐diaryl‐3,4‐dibromothiophenes, and tetraarylthiophenes. Unsymmetrical 2,5‐diaryl‐3,4‐dibromothiophenes are prepared by Suzuki r