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Synthesis of Terpenoid Lactones with the p-Menthane System

✍ Scribed by Iwona Dams; Agata Białońska; Zbigniew Ciunik; Czesław Wawrzeńczyk

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
157 KB
Volume
2004
Category
Article
ISSN
1434-193X

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Scheme 1 la, b a,lR b,lS 2a, b a,lR, 3R b,lS, 3s 3a, b a,lR, 3R b,lS, 3 s J (iii) 8 Sa, b 4a, b a, IR, 2S, 6R b, lS, 2 R, 6s a, lR, 2S, 6R b, l S , 2R, 6s Reagents (i) MeC(OEt)3, EtCOzH, 138', 48 h, ii) KOH, EtOH,reflux, (iii) J2, KJ, NaHCO3, Et20, (iv) (n Bu)3SnH, C6Hg Both myrtenols were subjecte