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Synthesis of syn and anti 1,4-Diols by Copper-Catalyzed Boration of Allylic Epoxides

โœ Scribed by Dr. Mariola Tortosa


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
313 KB
Volume
50
Category
Article
ISSN
0044-8249

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Desymmetrization of meso-2-Alkene-1,4-di
โœ Hajime Ito; Takuma Okura; Kou Matsuura; Masaya Sawamura ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 336 KB ๐Ÿ‘ 1 views

Desymmetrization reactions of meso compounds through enantioselective catalysis are a powerful strategy for the synthesis of chiral molecules with multiple stereocenters. One well-known example is the Pd-catalyzed desymmetrization of meso-2-alkene-1,4-diol derivatives (Trosts Pd-catalyzed asymmetric