Synthesis of supported titanocene amide complex and its use as a catalyst in ethylene polymerization
โ Scribed by Sari Timonen; Tuula T Pakkanen; Eero I Iiskola
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 162 KB
- Volume
- 148
- Category
- Article
- ISSN
- 1381-1169
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## Abstract TiCl~2~[salphen(diโ__t__Bu)] was synthesized, characterized and employed as preโcatalyst in ethylene homoโ and copolymerization with propylene, 1โoctene and 10โundecenโ1โol. Xโray diffraction study on the titanium complex revealed a distorted octahedral coordination of the central metal
## Abstract Middleโrange __n__โalkyl chlorides are the most suitable components among a variety of tested alkyl halides in the preparation process of the highly active TiโMg catalyst MTK~ST~. A material balance of the initial components RCl, THF and CCl~4~ revealed the formation of oligomers, chlor