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Synthesis of Sulfur-Containing Tricyclic Ring Systems by Means of Photoinduced Decarboxylative Cyclizations

✍ Scribed by Axel G. Griesbeck; Michael Oelgemöller; Johann Lex; Andreas Haeuseler; Michael Schmittel


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
481 KB
Volume
2001
Category
Article
ISSN
1434-193X

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An efficient pathway for the stereocontrolled synthesis of functionalized, angularly fused tricyclic ring systems from readily available (1-alkynyl)carbene complexes [(OC) 5 M C(OEt)-CCR] (M Cr, W; R Ph, c-C 6 H 9 ) is described. The synthesis involves the formation of a 1-metalla-1,3,5-hexatriene f