Synthesis of Sulfones from Organozinc Reagents, DABSO, and Alkyl Halides
โ Scribed by Rocke, Benjamin N.; Bahnck, Kevin B.; Herr, Michael; Lavergne, Sophie; Mascitti, Vincent; Perreault, Christian; Polivkova, Jana; Shavnya, Andrei
- Book ID
- 121797023
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 746 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1523-7060
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๐ SIMILAR VOLUMES
An efficient and selective method for the synthesis of sulfonic esters from sulfonic acids or sodium sulfonates using polymer-bound primary triazenes based upon the T2\* linker has been developed. The purities of the esters obtained are usually greater than 95% without any further purification steps
Here we report the utilization of commercially available p-toluenesulfon~lde as a new nucleophlk reagent in displacement reactions with suitable htildes for -an improved, genera/ synthesis of sulfones. Good results are obtained with primary, secondary, af/ylic, benzyk, and aromatic halides activated