✦ LIBER ✦
Synthesis of Sugar Azido or Amino Esters and Their Use as Building Blocks for the Preparation of Saccharide Nucleosides
✍ Scribed by Juan Xie
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 172 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-193X
No coin nor oath required. For personal study only.
✦ Synopsis
Carbohydrates / Sugar amino acids / Sugar azido or amino esters / C-Glycoside analogues / Saccharide nucleosides Several sugar azido or amino esters bearing an α-or a β-C-Dglucopyranosyl backbone have been prepared by TMSOTf/ Ac 2 O-mediated α-C-glycosylation with concurrent selective removal of the primary benzyl group or selective acetolysis of the primary benzyl group of β-C-glycoside as key steps.