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Synthesis of substituted anthranils by deoxidation of o-nitrosoacetylbenzenes

โœ Scribed by Yu. S. Shabarov; S. S. Mochalov; A. N. Fedotov; V. V. Kalashnikov

Book ID
112326111
Publisher
Springer US
Year
1975
Tongue
English
Weight
192 KB
Volume
11
Category
Article
ISSN
0009-3122

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AuBr3-catalyzed cyclization of o-(alkyny
AuBr3-catalyzed cyclization of o-(alkynyl)nitrobenzenes. Efficient synthesis of isatogens and anthranils
โœ Naoki Asao; Kenichiro Sato; Yoshinori Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 120 KB

The cyclization of o-(arylalkynyl)nitrobenzenes was catalyzed by AuBr 3 to produce the corresponding isatogens in good to high yields together with small amounts of anthranils. On the other hand, anthranils were obtained selectively when the AuBr 3 -catalyzed reaction was carried out using o-(alkyla