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Synthesis of substituted 3-vinylpyridines

โœ Scribed by L. S. Novikov; V. A. Mezhentsev; I. G. Tishchenko

Book ID
112355591
Publisher
Springer US
Year
1979
Tongue
English
Weight
61 KB
Volume
15
Category
Article
ISSN
0009-3122

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๐Ÿ“œ SIMILAR VOLUMES

Triazolines. XXXIII. Nonregiospecific 1,
Triazolines. XXXIII. Nonregiospecific 1,3-cycloaddition of aryl azides to vinylpyridines: A unique route to the synthesis of 2-pyridyl substituted aziridines via unstable 4-pyridyltriazoline intermediates
โœ Zhaiwei Lin; Pankaja K. Kadaba ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 530 KB

The 1,3-cycloaddition of aryl azides to the olefinic bonds of 4- and 2-vinylpyridines has been found to yield pyridyl substituted aziridines as the main reaction products with only smaller amounts of the normally expected 1-aryl-5-pyridyl-1,2,3-triazolines. Theoretical and experimental evidence are