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Synthesis of Substituted 2‐Amino‐cyclobutanones

✍ Scribed by Armoush, Nicola; Syal, Preeti; Becker, Daniel P.

Book ID
120068236
Publisher
Taylor and Francis Group
Year
2008
Tongue
English
Weight
147 KB
Volume
38
Category
Article
ISSN
0039-7911

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An efficient and easy one-pot reaction from readily available racemic 2-substituted cyclobutanones gave, by means of asymmetric Strecker synthesis in the presence of an amine chiral auxiliary, two major aminonitriles with excellent diastereoselectivity. After separation, the major cis-aminonitriles