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Synthesis of steroidal dimers: Selective amine catalysed steroidal dimerization

✍ Scribed by SHAMSUZZAMAN; MOHD GULFAM ALAM; TABASSUM SIDDIQUI

Book ID
107584711
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2011
Tongue
English
Weight
147 KB
Volume
123
Category
Article
ISSN
0253-4134

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## Abstract Hydrolysis of 3β‐5‐diacetoxy‐5β‐cholestan‐6‐one oxime (1) gave seven products which, in addition to 3β‐acetoxy‐ and (6__E__)‐3β‐hydroxy‐5‐methoxy‐5α‐cholestan‐6‐one oxime (3 and 4), are identified as the dimeric steroids (6__E__,6′__E__)‐6‐(6′‐hydroxyimino‐5′α‐cholestan‐5′‐yl‐oximino)ch