๐”– Bobbio Scriptorium
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Synthesis of steroid compounds and related substances Communication XIX. Condensation of 3,4,4a,7,8,8a-hexahydro-4a methyl-5-vinyl-2(1H)-naphthalenone and 3,4,4a,5,6,8a-hexahydro-8a-methyl-8-vinyl-2(1H)-naphthalenone with 2-cyclohexen-1-ones and with citraconic anhydride

โœ Scribed by I. N. Nazarov; I. I. Zaretskaya; G. P. Verkholetova; I. V. Torgov


Book ID
112493564
Publisher
Springer
Year
1954
Tongue
English
Weight
877 KB
Volume
2
Category
Article
ISSN
1573-9171

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A practical synthesis of enantiomericall
โœ Akiko Saito; Akira Tanaka; Takayuki Oritani ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 274 KB

An asymmetric synthesis of (-)-geosmin 1 via highly diastereoselective reduction of the enantiomerically pure title ketone 3 is described. Diisobutylaluminum hydride reduction of 3 in a mixed solvent of tetrahydrofuran and 1,2-dimethoxyethane led to aUylic alcohol 4 in 96% d.e., which by recrystalli