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Synthesis of Sterically Hindered 1,3‐Diketones

✍ Scribed by Nandurkar, Nitin S.; Bhanushali, Mayur J.; Patil, Dinkar S.; Bhanage, Bhalchandra M.


Book ID
121273679
Publisher
Taylor and Francis Group
Year
2007
Tongue
English
Weight
148 KB
Volume
37
Category
Article
ISSN
0039-7911

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Acylation of Sterically Hindered 2-Propargyl-1,3-diketones. -The acylation of sterically hindered propargyl-substituted 1,3-diketones (I) by acyl chlorides occurs selectively at the terminal acetylenic group in the presence of CuCl. Some peculiarities of this reaction are reported. -(SHERGINA, S. I.