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Synthesis of Stereospecifically Deuterated Matairesinol, Podorhizol, Epipodorhizol, and Yatein

✍ Scribed by Neidigh, Kurt A.; Kingston, David G. I.; Lewis, Norman G.


Book ID
120274367
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
593 KB
Volume
57
Category
Article
ISSN
0163-3864

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Synthesis and spectroscopic stereospecif
✍ Thomas Ebner; Jochen Rebell; Peter Fischer; Claus O. Meese πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 French βš– 240 KB

Borohydride reduction of the (+)-1,t-dehydrosparteiniuni salts 2a,b proceeds almost exclusively from the Si side, yielding, respectively, the stereoselectively (2S)(J)-deuterated (-)-sparteine l c from 2a and NaB2H,, and the (tR)(a)-deuterated (-)-sparteiite Id from 2b and NaBH,. Stereochemistry and