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Synthesis of Star-Shaped Poly( p -Alkoxystyrenes) by Living Cationic Polymerization

โœ Scribed by Deng, Hai; Kanaoka, Shokyoku; Sawamoto, Mitsuo; Higashimura, Toshinobu

Book ID
126111355
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
257 KB
Volume
29
Category
Article
ISSN
0024-9297

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A four-armed star-shaped poly(tetrahydrofuran) (THF) having a pentaerythritol unit at the center of the molecule was synthesized from photoinduced cationic copolymerization of THF and pentaeryithritol tetrakis(3,4-epoxybutanoate) (PETE) in the presence of diphenyliodonium hexafluorophosphate. It was