## Abstract Summary: Well‐defined AB~2~ 3‐ and AB~4~ 5‐miktoarm star copolymers were prepared by combination of ring‐opening polymerization (ROP) and nitroxide‐mediated radical polymerization (NMRP) using dendritic tri‐ and penta‐functional initiators. Initially, two kinds of dendritic initiators h
✦ LIBER ✦
Synthesis of star-shaped PCL-b-PMMA/PSt from cyclotriphosphazene initiator by ring-opening polymerization and atom transfer radical polymerization
✍ Scribed by Weizhong Yuan; Xiaobin Huang; Xiaozhen Tang
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 250 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0170-0839
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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym