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Synthesis of Sr2PrO4: a Pr4+-containing oxide in the Sr2PbO4 structure type

✍ Scribed by Jeffrey E Fiscus; Hans-Conrad zur Loye

Book ID
117619026
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
516 KB
Volume
306
Category
Article
ISSN
0925-8388

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New phosphates, Sr1.9Cu4.1(PO4)4, Sr2Cu(PO4)2, and Sr9.1Cu1.4(PO4)7, were found in the Cu3(PO4)2+Sr3(PO4)2 system at 9003C under air. Sr1.9Cu4.1(PO4)4 crystallizes in an orthorhombic system with a ‫؍‬ 15.3695(7) A > , b ‫؍‬ 10.3652(4) A > , and c ‫؍‬ 7.9425(4) A > . Crystal structures of Sr9.1Cu1.4(