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Synthesis of Sphingosine Relatives, XVIII!. Synthesis of Penazetidine A, an Alkaloid Inhibitor of Protein Kinase C Isolated from the Marine Sponge Penares sollasi

✍ Scribed by Yajima, Arata ;Takikawa, Hirosato ;Mori, Kenji

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 819 KB
Volume: 1996
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199619960706

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✦ Synopsis

Abstract

Two stereoisomers of penazetidine A (1a), the azetidine alkaloid isolated from the Indo‐Pacific marine sponge Penares sollasi, were synthesized by starting from (S)‐serine and (R)‐or (S)‐citronellol. The natural penazetidine A must be either (2__S__,3__R__,4__S__,12′R)‐ or (2__S__,3__R__,4__S__,12′S)‐1a.

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