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Synthesis of some α-fluoroacryl esters

✍ Scribed by A. A. Muslinkin; N. M. Kapustina; N. N. Vyrina


Book ID
111462664
Publisher
SP MAIK Nauka/Interperiodica
Year
2009
Tongue
English
Weight
367 KB
Volume
82
Category
Article
ISSN
1070-4272

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Synthesis of 3,3-dichloro-2-fluoroacryli
✍ T. Nguyen; C. Wakselman 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 30 KB

Alcoxyperhalogenocyclopropanes I are easily prepared by dichlorocarbene addition to the halogenated enol ether derived from chlorotrifluoroethylene, under FIG conditions. Thermal opening of the cyclopropane ring leads to the formation of 3,3-dichloro--2-fluoroacrylic ester II by chlorine atom depart