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Synthesis of some tartaric acid derivatives

✍ Scribed by N. Katsaros; E. Vrachnou-Astra; J. Konstantatos; C.I. Stassinopoulou

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
240 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of dimethyltartaric, ducts of the reaction of V2+ diphenyltartaric and dibenryltartaric acids as proaqueous with pyruvic, phenylglyoxylic and phenylpyruvic acids is described.

Although the derivatives of tartaric acid, dimethyltartaric (4), diphenyltartaric (6), and dibenzyltartaric (6) acids have been known for some time there is no convenient method for their preparation in the literature. Dimethyltartaric' and diphenyltartaric acids2 have been prepared by photolysis of pyruvic and phenylglyoxylic acids in methanol and isopropyl alcohol respectively. Dibenzyltartaric acid has been prepared along with other products by reduction of an aqueous solution of the sodium salt of y-oxy-a-oxo-B,y-diphenylbutyric acid with sodium amalgam under an atmosphere of carbon dioxide?

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