## Abstract Methods for the synthesis of the title compounds with substituents at ring position 1, 3, and 6 are presented.
Synthesis of some pyrano[2,3-c]pyrazoles
β Scribed by James W. Pavlik; Vuthichai Ervithayasuporn; Supawan Tantayanon
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 105 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-152X
- DOI
- 10.1002/jhet.562
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β¦ Synopsis
Abstract
Synthetic methods have been developed to prepare pyrano[2,3βc]pyrazoles with various substituents at ring positions 1, 3, and 6. The ^1^Hβ and ^13^CβNMR properties of these products and their precursors are presented and discussed. J. Heterocyclic Chem., (2011).
π SIMILAR VOLUMES
## Abstract magnified image Novel __N__2βarylated pyrano[2,3β__c__]pyrazolβ6βones **2** can be prepared in a selective manner by generating the anion of **1** (**Rο£ΎH**) with lithium hexamethyldisilazide in DMF and quenching with activated aryl halides. Sterically demanding groups such as phenyl as
## Abstract magnified image An approach to pyrano[2,3β__c__]pyrazoles starting from spirocyclopropanepyrazoles __via__ a ringβopening/cyanomethylation and intramolecular cyclization is described. Reactions of spirocyclopropanepyrazoles **1a**, **1b**, **1c**, **1d** with chloroacetonitrile in the