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Synthesis of some C-glycosyl- and polyhydroxyalkyl-pyridazines

✍ Scribed by F.J. Lopez Aparicio; M. Plaza Lopez-Espinosa; R. Robles Diaz


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
478 KB
Volume
132
Category
Article
ISSN
0008-6215

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✦ Synopsis


be obtained by reduction of the e&o-peroxides 9a and 9b (derived from 8a and 8b, respectively) with dimethyl sulphide. The C + 0 rearrangement reported for C-glycosyl endo-peroxides' was also observed for 9a.


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## Abstract Some novel 3‐halo‐6‐(4‐substituted‐phenoxy)pyridazines and 3,6‐di‐(4‐substituted‐phenoxy)pyridazines were synthesized from 3,6‐dichloropyridazine or 3,6‐diiodopyridazine. 3,6‐Diiodopyridazine was prepared from 3,6‐dichloropyridazine using hydriodic acid/iodine monochloride.