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Synthesis of some alkyl metal selenolato complexes of zinc, cadmium and mercury. X-ray crystal structure of Me, Hg, Se(2,4,6-Pri3C62)

✍ Scribed by Manfred Bochmann; Andrew P. Coleman; Annie K. Powell


Book ID
108428534
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
542 KB
Volume
11
Category
Article
ISSN
0277-5387

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The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a Ο­